Just a note - talked to the local fuel distributor in this part of Germany a couple of years ago, and he had never heard of different summer/winter blends of gasoline. This is someone who picks up his fuel directly from the refinery, and not merely someone who has it delivered.

Of course, the extremes of temperatures are much less in Germany than a 'mild' state like Virginia, but I suspect that this is pretty much a distinctly North American practice, especially the stockpiling aspect. Possibly, German refineries simply adjust their output over time, without worrying excessively about the issue.

Even the northern states in the US have some hot days, so the summer blend becomes more of an issue.

Adding ethanol to the gasoline increases the problem of summer vaporization (wonderful!), so this may be another reason we have to be especially watchful. If we weren't putting ethanol in our gasoline, summer/winter blend would be less of an issue. I don't think Germany uses much ethanol to stretch its gasoline.

I believe the coming German ethanol mandate in gasoline is 10% from next March, and seems to be currently set at 5%.

However, there seems to be some 'flexibility' in this - the reasons for ethanol were related to climate change, and as further research shows the destructive habitat and social costs of bio-fuels, the EU has been reconsidering its general approach.

Mainly because ethanol is imported into the EU, and not manufactured within its borders, with fat subsidies for taking fossil fuels and converting them to ethanol. However, at least bio-diesel is working pretty well - Raps(rapeseed) grows pretty well in this area, and a good number of trucks are set up to use bio-diesel, and have been for several years at this point.

i am fairly sure there are differences between summer and winter fuel in Germany (and the UK) since I remember reading reports some yars ago about the addition of ethanol and tests of RVP. I guess that since Germany is a much smaller land area than the USA there is one national vlaue that is used rather tahn regional variations.

another guess is that there are EU regulatuions and standards.

Here in Yurop, Reid Vapour Pressure is expressed in kPa

For any of you who are preparing prudently (not hoarding) both the RVP and octane rating will fall over time.

You would think so, from a technical perspective at least, but this concept was completely unknown to the fuel distributor, including the idea of making sure to buy the correct blend of gasoline to store. Germany is not really a place noted for wide ranging curiosity, so it is possible that his not knowing about it merely reflects the fact that only people that really need to be concerned are those at the refinery.

Gail,
I don't think you have the whole picture.

Generally gasoline in cars needs a RVP between 5 and 15; 15 for easy vaporization (smoother running, acceleration)and 5 for slower vaporization(worse). OTH, if the RVP is too high you get vapor lock as the fuel vaporizes on warm days and the liquid doesn't get to the engine.

Refinery gasoline has a RVP of ~5, so to raise the blending 'average' RVP to 8 or 10 you have to add a small amount butane (RVP of 52!) or ethanol(RVP of 18) or MTBE(RVP of 8). In winter the tendency to evaporate is less because the ambient temperature is much lower.

You also HAVE to raise the (anti-knock)octane rating of gasoline with oxygenates (ethanol, MTBE(ether)) which replaced tetraethyl lead(poison). The octane number should be around 90. MTBE(ether) has an octane number(average) of 120, ethanol is 110, while refinery gasoline might have an octane rating of 85.

So producing a fuel that does two jobs which is always a balancing act.

To reduce ground level ozone(poison) producing smog from evaporating hydrocarbons, the EPA mandates that the RVP in summer be around 8(it varies around the country). Ethanol with an RVP of 18 does a better job keeping the RVP low than butane with an RVP of 52.

MTBE(ether) was found to be poisoning groundwater which is why it has been banned so you're left with basically ethanol to simultaneously lower RVP and raise octane.

If you have to blame somebody blame the EPA for requiring an average summer RVP of ~8. Then let the RVP rise with butane and be prepared for more ozone days.

Bottom line, ethanol is GOOD.

Ethanol with an RVP of 18 does a better job keeping the RVP low than butane with an RVP of 52.

But because ethanol is slightly polar, and gasoline isn't, the effect of adding ethanol has a greater impact on increasing the RVP. In other words, 10% ethanol will increase the RVP by more than 10% of ethanol's RVP. This is why the EPA had to grant RVP waivers for ethanol blends:

http://www.eia.doe.gov/oiaf/servicerpt/fuel/rvp.html

You can also read here of Dianne Feinstein's efforts to get a waiver from having to blend ethanol:

http://www.senate.gov/~feinstein/05releases/r-epa-oxygenate030905.htm

The California Air Resource Board (CARB) researched this issue at length and found that ethanol-blended gasoline does not help California meet the goals of the Clean Air Act as it relates to reducing ozone formation, particularly during the summertime, and, in fact, ethanol actually increases the emission of pollutants that cause ozone during the summer months.

Bottom line, ethanol is GOOD.

It's hardly that simplistic. It depends on how you make it and how you use it.

This is great topic! (note:...I just crashed, so if this shows up twice, forgive me)

I have a couple of questions...
1) Why is the RVP of ethanol 18? When I look up the vapor pressure ( wiki_ethanol ) it looks like at 100 F the vapor pressure is just over 100 mmHg, or 2-2.5 psi. Am I missing something, or is this a result of the significant deviation that leads to ethanol/benzene azeotropes? Everything I've looked up supports ethanol raising the RVP...except the numbers.

2) All this vapor pressure stuff is dependant on mole fractions, so a very small amount of butane by mass or volume can have a huge effect. Thus a 10% butane mix (mass) will be much greater than 10% by mole fraction, thus much more than 5.2 psi...is there really much butane in any but the coldest gasolines?

3) More of a thermo question. How does decreasing energy content relate to mileage? For example, let's say a hydrocarbon fuel has 100 j/mL, and ethanol has 60 j/mL (made up numbers for easy math). If the unadulterated fuel gives you 20 mpg, what would a 50/50 fuel give you? The energy content would be about 80 J/mL, and a simple calculation would suggest that that translates to 16 mpg (20% reduction).
-my question is whether it is this simple. I suggest that it should be worse, as work that goes into friction and heat will largely stay constant, meaning that the fraction of energy that goes into moving the car takes most of the loss. If half the fuel's energy moves the car then the original fuel used 50 j/mL for friction and heat. If we switched to the mix, 50 J taken from the 80 leaves only 30 for proplusion, for a 40% loss (50 to 30), or a drop in mileage to 12 mpg. Maybe there are advantages (less wasted heat?) that mitigate this?

thanks
-dr

btw...great to hear you live at ASPO, Mr. Rapier

Thanks for that first link....If I had waited a few minutes before my previous posting I mighta saved a little time!

Why is the RVP of ethanol 18?

It isn't, but my guess is that what he was reporting above was something like an 'effective RVP' when blending. Based on RVP only, ethanol should lower the RVP when added to gasoline. However it raises RVP as noted.

is there really much butane in any but the coldest gasolines?

It is at about 2% in the winter, and can get up to 12% or so in the winter depending on what else is in the blend.

Maybe there are advantages (less wasted heat?) that mitigate this?

Compression ratio can be made higher if octane is higher. Ethanol increases octane. In theory, you could build a car that gets much better gas mileage than you would expect from a straight BTU calculation by raising compression ratio. Think about diesel. It has only about 10-15% more BTUs than gasoline, but diesel engines get 30% or so better fuel efficiency. Why? Higher compression ratios.

btw...great to hear you live at ASPO, Mr. Rapier

After hearing me, Debbie Cook said that she would always read my essays now envisioning a southern accent. But what I didn't tell her is that I actually write with a British accent. :-)

The RVP of denatured ethanol is 3psi , but the RVP of ethanol above a gasohol mix is 18( vapor pressure varies per Henry's Law). The reference below says 17 but I've seen 18 psi in other places. So for purposes of what I am talking about the RVP of ethanol to be added to gasoline mix is 18psi(17psi) and I standby it.

The RVP of gasoline product prior to blending can very greatly depending on where it comes from in the refinery--allkylate or reformate gasoline has a different RVP than FCC cracked gasoline and the amount of these 'gasolines' depends on the kind of oil supplied to the refinery. Reformate or FCC gasoline typically has RVPs of less than 5, so blending in butane, ether or ethanol is necessary.
The reason you can't reduce the RVP below 5 psi is that you'd have starting problems from low rates of fuel evaporation.

http://www.ethanolrfa.org/objects/pdf/newRFA%20Fuel%20Ethanol%20960501.pdf

R^2,
I don't understand your comment about polarity. MTBE ether is also polar. Do you recommend putting lead into gasoline?
At any rate Feinstein wanted to waive the whole oxygenate requirement. Oxygenates improve performance and reduce the production of carbon monoxide, isn't this important?

As far as the 10% allowance for ethanol goes, the EIA example assumes 9psi RVP gasoline prior to blending. I suppose a refinery could make one pre-blend for ethanol and a different RVP for straight gas to be used if the EPA requirements were too tight.

I don't understand your comment about polarity. MTBE ether is also polar.

Minor compared to ethanol. Ethanol is much less like a hydrocarbon, thus it doesn't mix as well.

Do you recommend putting lead into gasoline?

You throw out a lot of straw men? I have blended millions of barrels of gasoline. I have blended very high octane gasoline. I never used ethanol, MTBE, or lead.

Good stuff, thanks.

BAck to my mpg question. Assuming my '99 Tacoma is not re-tuned when I put gasoline with ethanol in it, what happens to my mileage? I assume the car is smart enough to adjust the air mix and the timing, but then what? 10% ethanol drops the energy content by 3% relative to the straight hydrocarbon fuel. In practice does anyone know (via careful tests) what that does to mileage? This seems an important part of the arguments for or against using ethanol as motor fuel. I recognize that adding ehtanol likely means removing other high octane components from the original fuel so exact comparisons are of limited value, but...?

Is there some rough equation that relates energy content to mileage?

(mileage) = EC * a where EC is energy content and "a" is a proportionality constant
or
(mileage) = (EC - b)*a where b is energy lost to friction/heat

-d

In practice does anyone know (via careful tests) what that does to mileage?

There have been a number of independent tests done, and they show the expected decline in mpg. Most of these are on E85 though:

http://www.consumerreports.org/cro/cars/new-cars/news/2006/ethanol-10-06...

I have around here somewhere a University of Wisconsin-Milwaukee study from the 90's that looked at 5% ethanol blends, and concluded that they dropped fuel efficiency by around 2%. The American Coalition of Ethanol commissioned a study recently and came out with the conclusion that fuel efficiency generally drops, but by less than the BTUs would warrant. The ethanol guys like that study, but I don't suppose they would like a study funded by the American Petroleum institute that concluded just the opposite.