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What happens next depends on the wind speed and direction. The cold methane will hug the ground; on land it will follow low points like valleys or streets. As it starts to mix with the surrounding air an opaque cloud will form from the condensation of water vapor. How fast it mixes depends on the wind turbulence. You would first get a severe asphyxiation danger from the cloud and then an explosion danger. If the cloud reaches the explosive limit then something like a automobile distributor could set it off.
Question: how much BCF can be on one tanker, and if there was a problem, what is the size that that gas would expand to? In other words, how big is a billion cubic feet of gas in the air? I assume 1 billion cubic feet is 1000x1000x1000 so is a cube the size of three lengths of football fields on each side (per bcf)
probably increasing in future to 200K m3 of tank vol => 4 BSCF
Tanks are thinner towards the top and looks like future tankers will be using aluminum tanks to save weight.
Sandia Labs study classifies a successful terrorist attack on an LNG tanker as a, "Low probability, high consequence event." Radiated heat would be damaging within a 1 mile radius.