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I cannot limit my nomination to a single post, because it was the several Robert Rapier posts on ethanol and Khosla that made the biggest impression on me. If I had to list one single post I'd be in a tough spot, because there were about ten or a dozen tied for first place, and from all of the editors, contributors and senior contributors on on the list. Probably of all the contributors, Khebab most influenced my thinking, but that is just edging by a hair others from first place. Where would we be without Stuart's posts?
Darn it all, just picking one posting does not work for me.
Leanan made large numbers of the best comments; I rate her input as A++.
posts on ethanol
Would that be the ones where ethonal powered cars get better milage per gallon than gas fueled cars?
Certainly--when you're right, you're right:-)
Here is Figure 2 from "Methanol: A Versatile Fuel for Immediate Use" by T. B. Reed and R. M. Lerner; Science, December 28, 1973, Volume 182, page 1301:

Sometimes 2 + 1 = 4. I don't know if anyone ever found similar results for ethanol, if so, they were never published in Science.